An equilibrium analysis to determine the speciation of metals in an incinerator

Chang Y. Wu, Pratim Biswas

Research output: Contribution to journalArticlepeer-review

137 Scopus citations

Abstract

An equilibrium analysis is carried out to determine the speciation of metals among their various forms in an incinerator. The Gibbs free energy of the system is minimized by the method of element chemical potentials combined with atom population constraints using a thermodynamic equilibrium computer code. Ninety-one compounds of six metallic species-arsenic, cadmium, chromium, lead, mercury, and tin-are analyzed in this study. The effect of temperature and chlorine content on the speciation is established. The effect of combustion of hydrocarbon fuels on the equilibrium calculations is also evaluated.

Original languageEnglish (US)
Pages (from-to)31-40
Number of pages10
JournalCombustion and Flame
Volume93
Issue number1-2
DOIs
StatePublished - Apr 1993
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)
  • Fuel Technology
  • Energy Engineering and Power Technology
  • Physics and Astronomy(all)

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