Addition of Pt(PBut3) to osmium-tin cluster complexes

Richard D. Adams, Burjor Captain, Lei Zhu

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

The reactions of the osmium-tin cluster complexes Os3(CO) 123-SnPh)Ph, 9, and Os4(CO) 164-Sn), 10, with Pt(PBut 3)2 have been investigated. Two products, PtOs 3(CO)12(Ph)(PBut3)(μ3- SnPh), 11, and Pt2Os3(CO)122- Ph)(PBut3)23-SnPh), 12, were obtained from the reaction of 9 with Pt(PBut3) 2. These are mono- and bis-Pt(PBut3) adducts of 9 formed by the addition of a Pt(PBut3) group to the Os-Os bond in 11 and the Os-Os bond and Os-C bond to the σ-bonded phenyl group in 12. A PBut3 derivative of 11, Os 2(CO)83-SnPh)Os(CO)3(PBu t3)Ph, 13, was obtained by treating 12 with PBu t3. The reaction of 10 with Pt(PBut 3)2 provided the bis-Pt(PBut3) adduct Os4(CO)16[Pt(PBut3)] 24-Sn), 14, that was formed by the addition of a Pt(PBut3) group across the Os-Os bond of both Os2(CO) 8 groups in 10. All four new compounds 11-14 were characterized by single-crystal X-ray diffraction analysis.

Original languageEnglish
Pages (from-to)4605-4611
Number of pages7
JournalInorganic Chemistry
Volume46
Issue number11
DOIs
StatePublished - May 28 2007
Externally publishedYes

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Osmium
Tin
osmium
X ray diffraction analysis
tin
Single crystals
Derivatives
adducts
single crystals
products
diffraction
x rays

ASJC Scopus subject areas

  • Inorganic Chemistry

Cite this

Addition of Pt(PBut3) to osmium-tin cluster complexes. / Adams, Richard D.; Captain, Burjor; Zhu, Lei.

In: Inorganic Chemistry, Vol. 46, No. 11, 28.05.2007, p. 4605-4611.

Research output: Contribution to journalArticle

Adams, Richard D. ; Captain, Burjor ; Zhu, Lei. / Addition of Pt(PBut3) to osmium-tin cluster complexes. In: Inorganic Chemistry. 2007 ; Vol. 46, No. 11. pp. 4605-4611.
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abstract = "The reactions of the osmium-tin cluster complexes Os3(CO) 12(μ3-SnPh)Ph, 9, and Os4(CO) 16(μ4-Sn), 10, with Pt(PBut 3)2 have been investigated. Two products, PtOs 3(CO)12(Ph)(PBut3)(μ3- SnPh), 11, and Pt2Os3(CO)12(μ2- Ph)(PBut3)2(μ3-SnPh), 12, were obtained from the reaction of 9 with Pt(PBut3) 2. These are mono- and bis-Pt(PBut3) adducts of 9 formed by the addition of a Pt(PBut3) group to the Os-Os bond in 11 and the Os-Os bond and Os-C bond to the σ-bonded phenyl group in 12. A PBut3 derivative of 11, Os 2(CO)8(μ3-SnPh)Os(CO)3(PBu t3)Ph, 13, was obtained by treating 12 with PBu t3. The reaction of 10 with Pt(PBut 3)2 provided the bis-Pt(PBut3) adduct Os4(CO)16[Pt(PBut3)] 2(μ4-Sn), 14, that was formed by the addition of a Pt(PBut3) group across the Os-Os bond of both Os2(CO) 8 groups in 10. All four new compounds 11-14 were characterized by single-crystal X-ray diffraction analysis.",
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N2 - The reactions of the osmium-tin cluster complexes Os3(CO) 12(μ3-SnPh)Ph, 9, and Os4(CO) 16(μ4-Sn), 10, with Pt(PBut 3)2 have been investigated. Two products, PtOs 3(CO)12(Ph)(PBut3)(μ3- SnPh), 11, and Pt2Os3(CO)12(μ2- Ph)(PBut3)2(μ3-SnPh), 12, were obtained from the reaction of 9 with Pt(PBut3) 2. These are mono- and bis-Pt(PBut3) adducts of 9 formed by the addition of a Pt(PBut3) group to the Os-Os bond in 11 and the Os-Os bond and Os-C bond to the σ-bonded phenyl group in 12. A PBut3 derivative of 11, Os 2(CO)8(μ3-SnPh)Os(CO)3(PBu t3)Ph, 13, was obtained by treating 12 with PBu t3. The reaction of 10 with Pt(PBut 3)2 provided the bis-Pt(PBut3) adduct Os4(CO)16[Pt(PBut3)] 2(μ4-Sn), 14, that was formed by the addition of a Pt(PBut3) group across the Os-Os bond of both Os2(CO) 8 groups in 10. All four new compounds 11-14 were characterized by single-crystal X-ray diffraction analysis.

AB - The reactions of the osmium-tin cluster complexes Os3(CO) 12(μ3-SnPh)Ph, 9, and Os4(CO) 16(μ4-Sn), 10, with Pt(PBut 3)2 have been investigated. Two products, PtOs 3(CO)12(Ph)(PBut3)(μ3- SnPh), 11, and Pt2Os3(CO)12(μ2- Ph)(PBut3)2(μ3-SnPh), 12, were obtained from the reaction of 9 with Pt(PBut3) 2. These are mono- and bis-Pt(PBut3) adducts of 9 formed by the addition of a Pt(PBut3) group to the Os-Os bond in 11 and the Os-Os bond and Os-C bond to the σ-bonded phenyl group in 12. A PBut3 derivative of 11, Os 2(CO)8(μ3-SnPh)Os(CO)3(PBu t3)Ph, 13, was obtained by treating 12 with PBu t3. The reaction of 10 with Pt(PBut 3)2 provided the bis-Pt(PBut3) adduct Os4(CO)16[Pt(PBut3)] 2(μ4-Sn), 14, that was formed by the addition of a Pt(PBut3) group across the Os-Os bond of both Os2(CO) 8 groups in 10. All four new compounds 11-14 were characterized by single-crystal X-ray diffraction analysis.

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