A self-complexing [2]catenane

Beatriz Cabezon, Jianguo Cao, Francisco Raymo, J. Fraser Stoddart, Andrew J P White, David J. Williams

Research output: Contribution to journalArticle

22 Citations (Scopus)

Abstract

A supramolecular homodimer is formed in solution and in the solid state by a self-complementary [2]catenane incorporating a 1,5-dioxynaphthalene- based macrocyclic polyether interlocked with a bipyridinium-based tetracationic cyclophane (shown schematically). This unique example of self- recognition is the result of a combination of cooperative π···π and C- H···π interactions.

Original languageEnglish
Pages (from-to)148-151
Number of pages4
JournalAngewandte Chemie - International Edition
Volume39
Issue number1
DOIs
StatePublished - Jan 3 2000
Externally publishedYes

Fingerprint

Polyethers
catenane

Keywords

  • Catenanes
  • Homodimeric complexes
  • Molecular recognition
  • Supramolecular chemistry

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

A self-complexing [2]catenane. / Cabezon, Beatriz; Cao, Jianguo; Raymo, Francisco; Stoddart, J. Fraser; White, Andrew J P; Williams, David J.

In: Angewandte Chemie - International Edition, Vol. 39, No. 1, 03.01.2000, p. 148-151.

Research output: Contribution to journalArticle

Cabezon, Beatriz ; Cao, Jianguo ; Raymo, Francisco ; Stoddart, J. Fraser ; White, Andrew J P ; Williams, David J. / A self-complexing [2]catenane. In: Angewandte Chemie - International Edition. 2000 ; Vol. 39, No. 1. pp. 148-151.
@article{0723a17d7e2d4a6d8af6e5d88a4fcd31,
title = "A self-complexing [2]catenane",
abstract = "A supramolecular homodimer is formed in solution and in the solid state by a self-complementary [2]catenane incorporating a 1,5-dioxynaphthalene- based macrocyclic polyether interlocked with a bipyridinium-based tetracationic cyclophane (shown schematically). This unique example of self- recognition is the result of a combination of cooperative π···π and C- H···π interactions.",
keywords = "Catenanes, Homodimeric complexes, Molecular recognition, Supramolecular chemistry",
author = "Beatriz Cabezon and Jianguo Cao and Francisco Raymo and Stoddart, {J. Fraser} and White, {Andrew J P} and Williams, {David J.}",
year = "2000",
month = "1",
day = "3",
doi = "10.1002/(SICI)1521-3773(20000103)39:1<148::AID-ANIE148>3.0.CO;2-7",
language = "English",
volume = "39",
pages = "148--151",
journal = "Angewandte Chemie - International Edition",
issn = "1433-7851",
publisher = "John Wiley and Sons Ltd",
number = "1",

}

TY - JOUR

T1 - A self-complexing [2]catenane

AU - Cabezon, Beatriz

AU - Cao, Jianguo

AU - Raymo, Francisco

AU - Stoddart, J. Fraser

AU - White, Andrew J P

AU - Williams, David J.

PY - 2000/1/3

Y1 - 2000/1/3

N2 - A supramolecular homodimer is formed in solution and in the solid state by a self-complementary [2]catenane incorporating a 1,5-dioxynaphthalene- based macrocyclic polyether interlocked with a bipyridinium-based tetracationic cyclophane (shown schematically). This unique example of self- recognition is the result of a combination of cooperative π···π and C- H···π interactions.

AB - A supramolecular homodimer is formed in solution and in the solid state by a self-complementary [2]catenane incorporating a 1,5-dioxynaphthalene- based macrocyclic polyether interlocked with a bipyridinium-based tetracationic cyclophane (shown schematically). This unique example of self- recognition is the result of a combination of cooperative π···π and C- H···π interactions.

KW - Catenanes

KW - Homodimeric complexes

KW - Molecular recognition

KW - Supramolecular chemistry

UR - http://www.scopus.com/inward/record.url?scp=0034598541&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0034598541&partnerID=8YFLogxK

U2 - 10.1002/(SICI)1521-3773(20000103)39:1<148::AID-ANIE148>3.0.CO;2-7

DO - 10.1002/(SICI)1521-3773(20000103)39:1<148::AID-ANIE148>3.0.CO;2-7

M3 - Article

AN - SCOPUS:0034598541

VL - 39

SP - 148

EP - 151

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

SN - 1433-7851

IS - 1

ER -