A novel composite photocatalyst for water splitting hydrogen production

Honghui Yang, Liejin Guo, Wei Yan, Hongtan Liu

Research output: Contribution to journalArticle

76 Citations (Scopus)

Abstract

A novel composite photocatalyst, Pt-TiO2-xNx-WO3 was synthesized by the template method and characterized by X-ray diffraction (XRD), ultraviolet-visible light diffusion spectroscopy (UV-vis), and element analysis. XRD spectra indicated that the photocatalyst was in anatase form and the diagnostic peak for WO3 existed. Combined with the XRD spectra and the results of elemental analysis, the formula of the composite photocatalyst was determined to be Pt-TiO2-xNx-WO3. UV-vis spectra showed the absorption edge was red-shifted to around 750 nm. Under the irradiation of ultraviolet, and with Na2S/Na2SO3 as the sacrificial reagent, the composite photocatalyst showed higher hydrogen production activity than anatase TiO2, and under irradiation with visible light (λ > 400 nm) it showed higher hydrogen production activity than TiO2-xNx while the anatase TiO2 showed negligible activity. An explanation was put forward for the mechanism of the red-shift of the absorption edge and the hydrogen production activity improvement.

Original languageEnglish
Pages (from-to)1305-1309
Number of pages5
JournalJournal of Power Sources
Volume159
Issue number2
DOIs
StatePublished - Sep 22 2006

Fingerprint

water splitting
hydrogen production
Photocatalysts
Hydrogen production
anatase
Titanium dioxide
composite materials
Water
Composite materials
X ray diffraction
diffraction
Irradiation
Spectroscopy
irradiation
x rays
red shift
spectroscopy
reagents
Catalyst activity
templates

Keywords

  • Composite photocatalyst
  • Hydrogen production
  • Nitrogen-doped titania
  • Photocatalyst

ASJC Scopus subject areas

  • Electrochemistry
  • Fuel Technology
  • Materials Chemistry
  • Energy (miscellaneous)

Cite this

A novel composite photocatalyst for water splitting hydrogen production. / Yang, Honghui; Guo, Liejin; Yan, Wei; Liu, Hongtan.

In: Journal of Power Sources, Vol. 159, No. 2, 22.09.2006, p. 1305-1309.

Research output: Contribution to journalArticle

Yang, Honghui ; Guo, Liejin ; Yan, Wei ; Liu, Hongtan. / A novel composite photocatalyst for water splitting hydrogen production. In: Journal of Power Sources. 2006 ; Vol. 159, No. 2. pp. 1305-1309.
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