A new living emulsion polymerization mechanism: Episulfide anionic polymerization

A. Rehor, N. Tirelli, J. A. Hubbell

Research output: Contribution to journalArticlepeer-review

67 Scopus citations

Abstract

The anionic ring-opening polymerization of episulfides has been successfully applied in emulsion. The polymerization proceeded with a living mechanism but was characterized by a limiting conversion, presumably arising from the increase in viscosity in the polymer. To the knowledge of the authors, only two other cases of living anionic polymerization in emulsion are known (silicones and cyanoacrylates); the additional novelty presented by episulfides is the ease of end-functionalization. Furthermore, the emulsion polymerization allowed the preparation of highly stable particles, which, due to their PEGylated surface and their appropriate diameter, can be applied in the biomedical field as nanocarriers.

Original languageEnglish (US)
Pages (from-to)8688-8693
Number of pages6
JournalMacromolecules
Volume35
Issue number23
DOIs
StatePublished - Nov 5 2002

ASJC Scopus subject areas

  • Organic Chemistry
  • Polymers and Plastics
  • Inorganic Chemistry
  • Materials Chemistry

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