A luminescence and electrochemical study of photoinduced electron transfer within the layers of zirconium phosphate

Ernesto Brunet, Marina Alonso, Carlos Cerro, Olga Juanes, Juan Carlos Rodríguez-Ubis, Angel Kaifer

Research output: Contribution to journalArticle

20 Citations (Scopus)

Abstract

Electron donors based on Ru(bpy)3 (bpy = 2,2′-bipyridine) are covalently attached to the walls of γ-ZrP and acceptor species based on viologen are arranged side by side following quite simple experimental protocols. The resulting materials are characterized by using the usual techniques and their luminescence and electrochemical properties are assessed. Strong evidence is presented of the efficient occurrence of photoinduced electron transfer in the solid state among the active species attached to the transparent inorganic matrix. The prepared materials may find applications in the clean conversion of light into useful energy.

Original languageEnglish
Pages (from-to)1603-1610
Number of pages8
JournalAdvanced Functional Materials
Volume17
Issue number10
DOIs
StatePublished - Jul 9 2007

Fingerprint

Zirconium
Luminescence
phosphates
electron transfer
Phosphates
Viologens
luminescence
Electrons
Electrochemical properties
occurrences
solid state
matrices
electrons
zirconium phosphate
energy
tris(2,2'-bipyridine)ruthenium II

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Materials Science(all)
  • Condensed Matter Physics
  • Physics and Astronomy (miscellaneous)

Cite this

A luminescence and electrochemical study of photoinduced electron transfer within the layers of zirconium phosphate. / Brunet, Ernesto; Alonso, Marina; Cerro, Carlos; Juanes, Olga; Rodríguez-Ubis, Juan Carlos; Kaifer, Angel.

In: Advanced Functional Materials, Vol. 17, No. 10, 09.07.2007, p. 1603-1610.

Research output: Contribution to journalArticle

Brunet, Ernesto ; Alonso, Marina ; Cerro, Carlos ; Juanes, Olga ; Rodríguez-Ubis, Juan Carlos ; Kaifer, Angel. / A luminescence and electrochemical study of photoinduced electron transfer within the layers of zirconium phosphate. In: Advanced Functional Materials. 2007 ; Vol. 17, No. 10. pp. 1603-1610.
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