A dynamic rearrangement of a metal cluster in a process that closely resembles the hopping mechanism of adatom diffusion on metal surfaces

Richard D. Adams; Burjor Captain; Wei Fu; Perry J. Pellechia; Mark D. Smith

doi:10.1002/1521-3773(20020603)41:11<1951::AID-ANIE1951>3.0.CO;2-T

A dynamic rearrangement of a metal cluster in a process that closely resembles the hopping mechanism of adatom diffusion on metal surfaces

Richard D. Adams, Burjor Captain, Wei Fu, Perry J. Pellechia, Mark D. Smith

Research output: Contribution to journal › Article › peer-review

42 Scopus citations

Abstract

Metal in motion: The reaction of [Ru₅(CO)₁₅(μ₅-C)] with [Pt(PtBu₃)₂] yields [Ru₅Pt(PtBu₃)(CO)₁₅(C)]. The product exists as two isomers, an open and a closed form, which interconvert rapidly on the NMR timescale by a process that resembles the diffusion of metal adatoms across a metal surface (see scheme; at 20°C the rate = 24000 s^-1).

Original language	English (US)
Pages (from-to)	1951-1953
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	41
Issue number	11
DOIs	https://doi.org/10.1002/1521-3773(20020603)41:11<1951::AID-ANIE1951>3.0.CO;2-T
State	Published - Jun 3 2002
Externally published	Yes

Keywords

Cluster compounds
Platinum
Rearrangements
Ruthenium

ASJC Scopus subject areas

Chemistry(all)

Access to Document

10.1002/1521-3773(20020603)41:11<1951::AID-ANIE1951>3.0.CO;2-T

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A dynamic rearrangement of a metal cluster in a process that closely resembles the hopping mechanism of adatom diffusion on metal surfaces. / Adams, Richard D.; Captain, Burjor; Fu, Wei; Pellechia, Perry J.; Smith, Mark D.

In: Angewandte Chemie - International Edition, Vol. 41, No. 11, 03.06.2002, p. 1951-1953.

Research output: Contribution to journal › Article › peer-review

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