Abstract
Metal in motion: The reaction of [Ru5(CO)15(μ5-C)] with [Pt(PtBu3)2] yields [Ru5Pt(PtBu3)(CO)15(C)]. The product exists as two isomers, an open and a closed form, which interconvert rapidly on the NMR timescale by a process that resembles the diffusion of metal adatoms across a metal surface (see scheme; at 20°C the rate = 24000 s-1).
Original language | English (US) |
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Pages (from-to) | 1951-1953 |
Number of pages | 3 |
Journal | Angewandte Chemie - International Edition |
Volume | 41 |
Issue number | 11 |
DOIs | |
State | Published - Jun 3 2002 |
Externally published | Yes |
Keywords
- Cluster compounds
- Platinum
- Rearrangements
- Ruthenium
ASJC Scopus subject areas
- Chemistry(all)