A comparison between zeolite-solvent slurry and dry solid photolyses

Vaidhyanathan Ramamurthy, D. R. Corbin, N. J. Turro, Z. Zhang, M. A. Garcia-Garibay

Research output: Contribution to journalArticle

43 Citations (Scopus)

Abstract

The use of a zeolite-solvent slurry as a convenient medium to carry out photoreactions is illustrated with four examples, namely Norrish type I reaction of dibenzyl ketones, Norrish type I and type II reactions of α-alkylbenzyl benzyl ketones, Norrish type II reaction of aryl alkyl ketones, and photodimerization of acenaphthylene. Solvent present within the supercages of zeolites X and Y provides constraint on the mobility of the included guest molecules. Such restrictions are reflected in the product distributions. The difference in the product distribution obtained between the zeolite-solvent slurry and a homogeneous solution is often higher than that between the dry powder zeolites and a homogeneous solution.

Original languageEnglish
Pages (from-to)255-261
Number of pages7
JournalJournal of Organic Chemistry
Volume56
Issue number1
StatePublished - Dec 1 1991
Externally publishedYes

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Zeolites
Photolysis
Ketones
Powders
Molecules

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

Ramamurthy, V., Corbin, D. R., Turro, N. J., Zhang, Z., & Garcia-Garibay, M. A. (1991). A comparison between zeolite-solvent slurry and dry solid photolyses. Journal of Organic Chemistry, 56(1), 255-261.

A comparison between zeolite-solvent slurry and dry solid photolyses. / Ramamurthy, Vaidhyanathan; Corbin, D. R.; Turro, N. J.; Zhang, Z.; Garcia-Garibay, M. A.

In: Journal of Organic Chemistry, Vol. 56, No. 1, 01.12.1991, p. 255-261.

Research output: Contribution to journalArticle

Ramamurthy, V, Corbin, DR, Turro, NJ, Zhang, Z & Garcia-Garibay, MA 1991, 'A comparison between zeolite-solvent slurry and dry solid photolyses', Journal of Organic Chemistry, vol. 56, no. 1, pp. 255-261.
Ramamurthy V, Corbin DR, Turro NJ, Zhang Z, Garcia-Garibay MA. A comparison between zeolite-solvent slurry and dry solid photolyses. Journal of Organic Chemistry. 1991 Dec 1;56(1):255-261.
Ramamurthy, Vaidhyanathan ; Corbin, D. R. ; Turro, N. J. ; Zhang, Z. ; Garcia-Garibay, M. A. / A comparison between zeolite-solvent slurry and dry solid photolyses. In: Journal of Organic Chemistry. 1991 ; Vol. 56, No. 1. pp. 255-261.
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