3-Substituted-2,4-pentanedionates: Ligands for photoactive supramolecular assemblies

Jean Hubert Olivier, Jack Harrowfield, Raymond Ziessel

Research output: Contribution to journalArticlepeer-review

24 Scopus citations

Abstract

Synthetic routes for the construction of 3-substituted 2,4-pentadionate ligands are broadly surveyed. They involve sequential alkylation and arylation by numerous methods, including those based on reactions of coordinated ligands, and can provide access to various rationally designed ligands. Applications of such ligands in the synthesis of multichromophoric complexes are illustrated in some detail. Incorporation of 3-substituted 2,4-pentanedione units into mesomorphic and macromolecular structures is considered in relation to structural control of energy and electron transfer processes in photoactive systems. Aspects of the general supramolecular chemistry of complexes of 3-substituted-2,4-pentadionate ligands are briefly discussed to illustrate the utility of such species within the full range of 1,3-dionate chemistry.

Original languageEnglish (US)
Pages (from-to)11176-11188
Number of pages13
JournalChemical Communications
Volume47
Issue number40
DOIs
StatePublished - Oct 28 2011
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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