Abstract
The products formed when glucose is heated in aqueous sulphuric acid, with or without pretreatment with formic acid, have been separated and estimated. The major products are 1:6-anhydro-β-D-gluco-pyranose and -furanose, while the remainder consists of the group of glucose disaccharides, in which isomaltose and gentiobiose predominate. The amounts of sugars so formed provide a guide to the quantities of reversion products likely to be encountered as artefacts in the examination of the structures of polyglucoses by the method of partial acidic hydrolysis.
| Original language | English |
|---|---|
| Pages (from-to) | 586-592 |
| Number of pages | 7 |
| Journal | Journal of the Chemical Society (Resumed) |
| DOIs | |
| State | Published - Dec 1 1958 |
| Externally published | Yes |
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ASJC Scopus subject areas
- Chemistry(all)
Cite this
114. Quantitative aspects of the acid reversion of glucose. / Peat, Stanley; Whelan, William J.; Edwards, T. E.; Owen, O.
In: Journal of the Chemical Society (Resumed), 01.12.1958, p. 586-592.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - 114. Quantitative aspects of the acid reversion of glucose
AU - Peat, Stanley
AU - Whelan, William J.
AU - Edwards, T. E.
AU - Owen, O.
PY - 1958/12/1
Y1 - 1958/12/1
N2 - The products formed when glucose is heated in aqueous sulphuric acid, with or without pretreatment with formic acid, have been separated and estimated. The major products are 1:6-anhydro-β-D-gluco-pyranose and -furanose, while the remainder consists of the group of glucose disaccharides, in which isomaltose and gentiobiose predominate. The amounts of sugars so formed provide a guide to the quantities of reversion products likely to be encountered as artefacts in the examination of the structures of polyglucoses by the method of partial acidic hydrolysis.
AB - The products formed when glucose is heated in aqueous sulphuric acid, with or without pretreatment with formic acid, have been separated and estimated. The major products are 1:6-anhydro-β-D-gluco-pyranose and -furanose, while the remainder consists of the group of glucose disaccharides, in which isomaltose and gentiobiose predominate. The amounts of sugars so formed provide a guide to the quantities of reversion products likely to be encountered as artefacts in the examination of the structures of polyglucoses by the method of partial acidic hydrolysis.
UR - http://www.scopus.com/inward/record.url?scp=0343190322&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0343190322&partnerID=8YFLogxK
U2 - 10.1039/JR9580000586
DO - 10.1039/JR9580000586
M3 - Article
SP - 586
EP - 592
JO - Journal of the Chemical Society
JF - Journal of the Chemical Society
SN - 0577-6171
ER -