Research Output

2008

Kinetic and thermodynamic studies of the reactivity of (trimethylsilyl) diazomethane with HMo(CO)3(C5R5) (R = H, Me). Estimation of the Mo-N2CH2SiMe3 bond strength and experimental determination of the enthalpy of formation of (trimethylsilyl)diazomethane

Fortman, G. C., Isrow, D., McDonough, J. E., Von Ragué Schleyer, P., Schaefer, H. F., Scott, B., Kubas, G. J., Kégl, T., Ungváry, F. & Hoff, C. D., Oct 13 2008, In : Organometallics. 27, 19, p. 4873-4884 12 p.

Research output: Contribution to journalArticle

1993

Nitrogen-15 NMR Studies of Tetrazole Complexes of Pentaamminecobalt(III). Implications Concerning the Transition State for Linkage Isomerization

Hubinger, S., Hall, J. H. & Purcell, W. L., Jan 1 1993, In : Inorganic Chemistry. 32, 11, p. 2394-2398 5 p.

Research output: Contribution to journalArticle

17 Scopus citations

Using cation-exchange resins in two experiments for the freshman laboratory

Purcell, W. L., Dec 1 1993, In : Journal of chemical education. 70, 7, p. 590-592 3 p.

Research output: Contribution to journalArticle

1 Scopus citations
1991

Solvent Effects on the Linkage Isomerization of the N1-Bonded Pentaamminecobalt(III) Complex of 5-Methyltetrazole

Hubinger, S. & Purcell, W. L., Sep 1 1991, In : Inorganic Chemistry. 30, 19, p. 3707-3710 4 p.

Research output: Contribution to journalArticle

14 Scopus citations
1990

Kinetic and Mechanistic Study of the Linkage Isomerization of Substituted (5-Phenyltetrazolato)pentaamminecobalt(III) Complexes

Hall, J. H. & Purcell, W. L., Jan 1 1990, In : Inorganic Chemistry. 29, 19, p. 3806-3811 6 p.

Research output: Contribution to journalArticle

14 Scopus citations
1989

Effects of anions on redox reactions. 2. chromium(II) reduction of [Co(sep)]3+ (sep = sepulchrate) in the presence of halide ions

Lewis, N. A., Purcell, W. L. & Taveras, D. V., Jan 1989, In : Inorganic Chemistry. 28, 1, p. 133-138 6 p.

Research output: Contribution to journalArticle

2 Scopus citations

Medium Effects in Weakly Coupled Electron-Transfer Processes: Calculation of Inner-Sphere Reorganizational Energies at Zero Ionic Strength

Lewis, N. A., Obeng, Y. S. & Purcell, W. L., Oct 1 1989, In : Inorganic Chemistry. 28, 20, p. 3796-3799 4 p.

Research output: Contribution to journalArticle

26 Scopus citations

Synthesis and Reactivity of Pyridine N-Oxide Complexes of Cobalt(III)

Purcell, W. L., Jun 1 1989, In : Inorganic Chemistry. 28, 12, p. 2312-2315 4 p.

Research output: Contribution to journalArticle

9 Scopus citations

The chemical mechanism for electron transfer and bridge reducibility

Purcell, W. L., 1989, In : Polyhedron. 8, 4, p. 563-565 3 p.

Research output: Contribution to journalArticle

1 Scopus citations
1986

Dichlorotetrakis(pyridine)cobalt(III): A Versatile and Facile synthetic Precursor

Purcell, W. L., Jan 1 1986, In : Inorganic Chemistry. 25, 23, p. 4068-4069 2 p.

Research output: Contribution to journalArticle

9 Scopus citations
1985

Kinetics of azide attack on organonitriles coordinated to pentaamminecobalt(III)

Hall, J. H., de la Vega, R. L. & Purcell, W. L., Aug 15 1985, In : Inorganica Chimica Acta. 102, 2, p. 157-162 6 p.

Research output: Contribution to journalArticle

31 Scopus citations
1983

Kinetics of Linkage Isomerization of (5-Methyltetrazolato)pentaamminecobalt(III)

Purcell, W. L., Apr 1983, In : Inorganic Chemistry. 22, 8, p. 1205-1208 4 p.

Research output: Contribution to journalArticle

26 Scopus citations

Kinetics of the Reduction of the Linkage Isomers of the Pentaamminecobalt(III) Complexes of 4-Cyanobenzoic Acid by Chromium(II)

Balahura, R. J., Kupferschmid, W. C. & Purcell, W. L., May 1983, In : Inorganic Chemistry. 22, 10, p. 1456-1461 6 p.

Research output: Contribution to journalArticle

2 Scopus citations

Preparation, Characterization, and Chromium (II) Reduction Kinetics of Tetrazole Complexes of Pentaamminecobalt(III)

Balahura, R. J., Purcell, W. L., Victoriano, M. E., Lieberman, M. L., Loyola, V. M., Fleming, W. & Fronabarger, J. W., Nov 1983, In : Inorganic Chemistry. 22, 24, p. 3602-3608 7 p.

Research output: Contribution to journalArticle

10 Scopus citations

Reactivity patterns in the base hydrolysis of coordinated aromatic nitriles

de la Vega, R. L., Ellis, W. R. & Purcell, W. L., 1983, In : Inorganica Chimica Acta. 68, C, p. 97-101 5 p.

Research output: Contribution to journalArticle

25 Scopus citations
1982

Linkage Isomers of 5-Methyl- and 5-Phenyltetrazolato(1−) Complexes of Pentaamminecobalt(III) and Their Isomerization Reactions

Ellis, W. R. & Purcell, W. L., Jan 1 1982, In : Inorganic Chemistry. 21, 2, p. 834-837 4 p.

Research output: Contribution to journalComment/debate

79 Scopus citations
1981

Neighboring-Group Participation in the Hydrolysis of Coordinated Nitriles

Balahura, R. J. & Purcell, W. L., Dec 1981, In : Inorganic Chemistry. 20, 12, p. 4159-4163 5 p.

Research output: Contribution to journalArticle

32 Scopus citations
1979

Novel Reactions of 1, 2-Disubstituted Benzenes Coordinated to Cobalt(III): Neighboring-Group Participation

Balahura, R. J. & Purcell, W. L., Jan 1 1979, In : Inorganic Chemistry. 18, 4, p. 937-941 5 p.

Research output: Contribution to journalArticle

29 Scopus citations
1976

Reduction of Pentaamminecobalt(III) Complexes of Aromatic Nitriles by Chromium(II)

Balahura, R. J. & Purcell, W. L., Jul 1 1976, In : Journal of the American Chemical Society. 98, 15, p. 4457-4462 6 p.

Research output: Contribution to journalArticle

8 Scopus citations
1975

Kinetics of the Chromium(II) Reduction of m- and p-Acetylbenzonitrile Complexes of Pentaamminecobalt(III). Observation of a Chromium (III) Intermediate

Balahura, R. J. & Purcell, W. L., Jul 1 1975, In : Inorganic Chemistry. 14, 7, p. 1469-1473 5 p.

Research output: Contribution to journalArticle

8 Scopus citations
1974

Kinetics Studies of the Hydrolysis of Coordinated Nitriles

Balahura, R. J., Cock, P. & Purcell, W. L., May 1 1974, In : Journal of the American Chemical Society. 96, 9, p. 2739-2742 4 p.

Research output: Contribution to journalArticle

40 Scopus citations
1970

Nitrogen-14 Nuclear Magnetic Resonance Studies of Acetonitrile Exchange from the First Coordination Sphere of Manganese(II)

Purcell, W. L. & Marianelli, R. S., Jul 1 1970, In : Inorganic Chemistry. 9, 7, p. 1724-1728 5 p.

Research output: Contribution to journalArticle

19 Scopus citations